Keep behind allied minions if Caitlyn is harassing you with Piltover Peacemaker (it deals less damage with each subsequent target).
You can intercept Ace in the Hole's missile from hitting an ally if you stand in its path.
The stat comparisons shown here emphasize several valuable Volibear vs. Caitlyn matchup stats that can help us interpret the differences and similarities between the pair. Volibear’s KDA ratio ([kills + assists] / deaths) of NaN is greater than Caitlyn’s KDA ratio of NaN, indicating that Volibear may be more central to his team's team fighting effectiveness than Caitlyn..
Volibear usually has a similar longest kill spree as his matchup does. Commonly, he receives more damage than Caitlyn. This often reflects differing health capacities, yet it can also indicate that the champion with increased health has less agility and thus is not able to kite away from additional harm when engaged or poked.
Both LoL champs are great champions. Both champs have their strengths, weaknesses, and counters. In the game's current meta, Volibear usually fairs equally well when trying to fight Caitlyn, with a 49.5% win rate. As a result, Volibear makes an ok counter for Caitlyn.
While Volibear does have a lower win rate than Caitlyn, when they face off with one another, Volibear also has a lower level of difficulty that makes him a less difficult champion to pick up and master. You still need to be cautious when picking Volibear into Caitlyn.
Moreover, Volibear has some amount of utility and CC, a similar amount to Caitlyn. This often makes her just as valuable during teamfights, especially when facing champions with a lot of burst damage.
While there isn't a single best champion overall in League of Legends, in Volibear vs Caitlyn matchups, Caitlyn is the better champion with a similar win rate, less champion complexity, and a similar amount of utility to help out your team members during team fights.
Volibear is a somewhat poor counter for Caitlyn. Focus your gameplay on maximizing your gold and cs and taking out objectives. If you do that, you should hold your own as Volibear against Caitlyn.
To truly master Volibear in order to counter Caitlyn during both the early game and mid / late game phases of League of Legends, you should keep reading to pick up a few extra lessons on this matchup. If you pay attention to the build and stats shown above, you should grow your win rate significantly and be that much closer to League of Legends pro players.
Volibear typically accumulates a similar amount of CS relative to Caitlyn. Champions who on average don't take many minion kills often don't need much CS to be valuable teammates, such as sup champs. They are able to scale well off of their skills, stats, and first items alone. Yet, champs with a lot of CS, such as hyper-carries, typically require a lot of items to be effective. In either situation, try to do better than the numbers shown on this page to do well.
The most important items to use in your Volibear versus Caitlyn build consist of Nashor's Tooth, Hullbreaker, and Jak'Sho, The Protean. When Volibear used at least these three pieces in his build, he did a lot better versus Caitlyn than with many other commonly used item sets. In fact, Volibear had an average winrate of 49.5% when playing against Caitlyn with this counter build.
To have the best chance of annihilating Caitlyn as Volibear, Volibear players should take the Lethal Tempo, Triumph, Legend: Alacrity, Last Stand, Demolish, and Revitalize runes from the Precision and Resolve rune sets. Out of all the runes players picked for Volibear vs Caitlyn battles, this order of runes resulted in the highest win rate. Moreover, these runes provided a 49.5% win rate overall.
If you want to view Volibear x Caitlyn tips and counter stats for a a particular player tier, feel free to choose one from the selection menu shown above. At first, the stats and guides shown are calculated using every match run with both champs.